I've heard of using phosphoric acid to "acidify" the StarSan solution.
5% Acetate (vinegar) does have a pH around 2.4, but I wonder whether it would be the ideal acid to use given that we want to use the StarSan solution as a "no rinse" sanitizer. Most beer styles we attempt to brew would get dinged for any "vinegar" or "acetic" aromas or flavor.