There aren't any chemical effects IME. You just need to make adjustments to fit the equipment, like changing to any other brew system, regardless of scale. Your boil-off will probably be proportionally less, for example.
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I don't drink RIS often, but when I do it's almost always Old Rasputin.
The reason I am worried about the wort that I aerated with the yeast in it is everything I have read has told me NOT to do that once the yeast is pitched.
I know I wont get the right flavor profile as a true Belgian, but that doesnt matter to me as long as the beer is drinkable!
the easiest route is to use a DAC