confirmed again today that when using distilled, my acutal PH is almost dead on to bru'nwater target PH. today bru'nwater projected 5.43, actual 5.41.
last brew with my RO water was bru'nwater projected 5.6 and actual 5.45 (right where I wanted it). perhaps as Martin said, carboninc acid in play and not accounted for in his software.