I mash in a plastic cooler, so obviously I'm not personally too concerned. Its not the same as microwaving things wrapped in plastic where the levels of toxicity are going to be high. Still, for someone trying to minimize their exposure to carcinogens the SS would be attractive. If I had cancer running in my family I would certainly be interested. I might be wrong, but I don't think there is much data about decades long cumulative exposure. Again, I think its OK to mash in plastic and I do, but I don't think we definitively know there is zero risk so if I were in a high risk group and there was an easy option to avoid a possibly small but not completely known risk, why not?
As for the ethanol analogy: known risks, known benefits. We are balancing some known health benefits and known health risks while factoring in our own physiology, effect on our personal lives etc. (or at least we can), while there is no known health benefit to mashing in plastic versus an unknown risk.