Hanging on to wort after boiling for a few days is an invitation to infection.
Overnight, not really a problem. The issue is that SOME microbes can make it into that wort after the boil. Pitching the yeast builds an environment that is hostile and they become outnumbered by the yeast. Leaving them without competition allows them to multiply if they are present. This is a low probability but non-zero risk.
"Normal" krausening is done using successive batches to achieve similar intent but without the risks of holding out unfermented wort. Otherwise, the differences are that both batches are (presumed) hopped identically, and you have the bigger added advantage that the new beer used to finish the old batch has vigorous, active yeast present. By contrast, your hopped krausen approach adds new complex fermentables to a batch which has yeast that have neared cycle completion. You _may_ get extra byproducts such as increased diacetyl, DMS, or other off flavors/aromas associated with weak fermentation by giving them more work to do on complex sugars (as opposed to simple fruit sugars, or Candi sugar, or priming sugar for comparison purposes).
I'm not saying it can't work. I'm just pointing out some of the potential issues.
Try it and compare it with normal krausening and letting a batch go to completion without adding anything. It would be a good experiment, I'd think.
My .02