I use 2.5G kegs exclusively. If you connect to 11-12PSI the keg will be fully carbonated in 7-10 days easy.
Higher pressure will over carbonate a 2.5G keg faster than a 5G. I don't know exactly how how long it takes to carb at higher pressure, but, I do know 30PSI for 24 hours over carbonated a keg for me in the past. I haven't tried again. 7-10 days is always fast enough for me since I like at least a little conditioning time.
PS. Boost carbing probably takes half the time since you are delivering half as many CO2 molecules to achieve the same carbonation volume.