t wondering was leaving my initial mash in the boil pot waiting for my sparge have caused DME production that will affect my final beer?
I think you meant DMS, not DME. No you didn't cause a DMS problem.
You may develop some "caramelized" flavors, which are really Maillard flavors, but they'll probably be hard to pick up in a Porter. Also the Maillard flavors will be low because the concentration of sugar wasn't that high in your boil. The extra boiling will make the beer darker but it'll be hard to notice that in a Porter.
RDWHAHB!