After spending a few minutes reviewing what TBI and TBA are, it is very apparent that this is a well known effect in the big boy breweries. Extended or intense boiling can actually "pre-damage" the wort and make the resulting beer age quicker.
At the homebrew level where we probably keep our beer cooler and consume it sooner, this issue may be moot. But to provide your beers with longer shelf life, you do need to consider this. I will definitely be reviewing my practices and be making some changes.
Thanks for bringing this up, gentleman.