Is a 90 minute boil absolutely necessary for pilsner malt?
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With the fervor at which us homebrewrs boil, this is not a thing. DMS is also a pH thing, the higher the pH the faster the removal. I am able to reliably produce dms with a low pH (5.2 at mash and start of boil), a low boil off% (sub 6%) and a 60 minute boil. So it can be a thing, just a FYI, and its horrible.
If I'm reading this correctly. During your experiments you were able to produce DMS, and in order to avoid it I should..
Keep mash pH higher than 5.2.
Boil off rate should be above 6% for 90 minutes.
I should probably start with a small batch and see what works for my system.
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I am just a single data point. I am not telling you really what to avoid, but more so what I have seen.
It's a tough dilemma: As there are draw backs to changing any of those variables.
What I have done with my system is to start to mash a little higher say 5.4, then I keep all other variables the same.
I get a little less oxidation reduction potential from the pH, but I get more alpha activity.
Boiling longer than 60 min can hurt foam, but may rid DMS if you have an issue. I wouldn't jump from 60 right to 90 if there is a problem, I would use increments of 10 minutes. YOu can smell when the DMS is gone.