I think if you follow these instruction you will be disappointed when the keg you thought was empty starts bubbling into your fermenter.
Dont pull the PRV. If you are using the bucket spigot, hook the hose up to your black QD first (assuming ball lock leg since you mentioned PRV. Also hook up a length of hose to the grey QD. This will go into a jar of sanitizer or water.
Snap the liquid disconnect to the post first and aim the open end away from your face. It will blow sanitizer that settled. As it winds down hook up the gas disconnect and put the open end in the sanitizer. Now hook up to your spigot and drain. I fill mine until beer comes out the gas post (I'm also using shortened gas tubes). Then push a cup or so of beer out after filling.
I brew 2.5g batches and ferment in 5g kegs. When time to package, I purge my receiving/serving keg with CO2. Then, I attach my CO2 to the gas in post on my fermenter. I then attach a jumper from my Beer Out on my fermenter to my beer out on my receiving keg. Ball lock disconnects on both ends, of course. I apply a small amount of CO2 pressure to my fermenter and very slowly unscrew my PRV on my receiving keg until I start to hear a hissing sound. At that point I stop and leave the PRV in that position for the entire fill. The hissing (which is essentially CO2 leaving my serving keg) continues throughout the entire filling process. Once done, I tighten the PRV and I'm done.
However, JT mentions a way of releasing the receiving kegs pressure without fiddling with the PRV and I love it! I never thought of simply attaching to the CO2 post on the receiving keg and just letting it bubble into a jar if sanitizer. That seems way easier than messing with the PRV. So I shall give that a try when I package my cream ale this week. Love it!