OK, I did some calculations using Martin's Bru'n Water program for your grain bill, HopDen. Here is what I came up with. The numbers are quite a bit different than the ones you originally posted but this profile has worked well for my Baltic Porters.
Water profile London (boiled)
CA 42
Mg 5
Na 17
SO4 40
Cl 39
HCO3 79
Alkalinity 65
Hardness 127
RA 32
SO4/Cl 1.0
Predicted mash pH with these additions 5.23. (I almost always get really close to this predicted pH number within the accuracy of my pH meter)
This yields the following salt amounts for the mash (in grams) for 21.5 gallons
Gypsum 2.8
Calcium Chloride 4.52
Epsom Salt 4.3
Canning Salt 0.43
Baking Soda 4.3
Pickling Lime 2.15
I then calculated the salt addition for "seasoning" the kettle wort (in grams) for 4 gallons, the difference between the mash volume and a kettle volume of 25 gallons.
Gypsum 0.46
Calcium Chloride 0.74
Epsom Salt 0.7
Canning Salt 0.07
No baking soda or pickling lime are added to the kettle.
As I said before and which Martin confirms, the only thing that goes into the sparge liquor is Phosphoric Acid to acidify the liquor to a pH of 5.2 - 5.6. I shoot for the same pH as the measured pH of the mash.
Hope this helps for a future brew of this style.