Have you considered puting it in an autoclave/pressure cooker to kill bugs?
First, I don't have an autoclave. Second, I never considered pressure cooker, but am wary of over heating and damaging the PTFE, seals, etc. I'd need to check spec sheets specifically, but I think most of these lower cost valves are rated somwhere in the ~240 - 260F range, and an autoclave with steam splits the difference.
Brew day post-brew cleaning is an extended recirculation with PBR followed by 200F water and a final sanitizer rinse through the system. I've measured 190+ sustained surface temp on valves, which ought to sanitize their interiors sufficiently---in effect similar to your autoclave/pressure cooker at lower temp.
It's the gunk build-up that occurs with valves where the ball chamber isn't fully encapsulated that concerns me. If there is anything growing on the accumulation, my approach might not be sufficient to knock it down. An extended trip in an autoclave would solve that, subject to the caveats above, but still leave the gunk behind.
Personally, I like to strip down valves every six or so brew days to clean out any gunk and prevent accumulation. Actually, I have my sons do it as part of brewing with me --- those who would drink must work.