Maybe I’m wrong here, but from what I understand, oxidation in the mash is caused by O2 reacting with divalent cations (manganese, magnesium, zinc — cations with valence of 2+) to create superoxide, free radicals.
Problem is once those oxidation reactions occur, the compounds created continue all the way thru to the packaged beer.
The Low O2 guys (I believe) have taken the approach to reduce/eliminate dissolved O2 in the mash thru use of sulfur based compounds, mash caps, etc.
Instead of focusing on reducing/elimination of O2, (which is kinda hard to do since it surrounds us), I think time is better spent focusing on the reaction.
I believe by using heavy metal chelators that can trap the divalent cations, you can reduce and possibly eliminate the reaction of mash oxidation.
In my opinion, you have a better chance on winning the reaction battle than the O2 battle short of a room filled with inert gas and wearing a space suit.
In the food world FDA approved EDTA does this. I think Brewtan B does as well (maybe Joe can confirm). I’ll report back on what Joe says from the note I sent him.
I add 1/2 tsp of hydrated Brewtan B directly to the mash after mash in, wait a minute, then add 1 tsp CaCl or Gypsum directly to the mash and focus on pH. The wait is so the Brewtan B is not binding with my Calcium (if that’s a thing).
After the mash danger is over, transferring hot wort quietly to the BK, boiling, cooling quickly and pitching plenty of healthy yeast, closed transfer to a purged keg as soon as fermentation is complete, and keeping the beer cold are all considered by some to be best practices.
Even closed xfer we pick up O2. It’s just inevitable and we do what we can. The rest is just the price of doing business.
Edit: Given that there is still yeast in suspension when I transfer, I hope I am using the yeast to my advantage by having them consume any O2 I inadvertently pickup.