Dirty keg? Or a somehow defective part in the keg? Scratched surface, something like that maybe.
When did you have the samples, right away and then a month later one was bad? If so, its something that happened after, so I would lean toward either a problem with the keg or a possible contamination.
Which did you rack first? Where are possible sources of copper and iron in your brewery? Apparently a little bit of metal can get worse over time, according to two master judges I spoke to recently.