mg/l & ppm are nearly interchangable.
Now...If you REALLY want to be picky, there are folks that can give you the breakdown.
But, for most applications, they are close enough.
I wouldn't brew with ANY water that is listed as unsafe for drinking.
I'm no chemist, but I'd be afraid that by boiling off a volume of the original water, I am effectively creating a concentration of the contaminants.