i think it depends on whether you are extract or all-grain brewing. it would be a hassle to mash just for a little wort to use as a starter, but if you are extract brewing, or don't mind using extract for a little batch of wort, i'd boil it up fresh in a little pot. your wort, (extract or all-grain, though more so in all-grain,) has fresh nutrients and natural chemicals that yeast really get off on, and they will degrade -- even minutely -- with time, so why not boil it up fresh?